Na & Mg With Water

01Na & Mg With Water

Sodium and water

This section covers the vigorous reaction of sodium with cold water, including its observations, products and oxidation-state change.

Reaction with cold water

Cold water reacts rapidly with sodium and releases a considerable amount of heat. Hydrogen is evolved and sodium hydroxide remains in solution.

2Na(s)+2HX2O(l)2NaOH(aq)+HX2(g)\ce{2Na(s) + 2H2O(l) -> 2NaOH(aq) + H2(g)}
  • The piece of sodium remains at the water surface.
  • Rapid gas evolution produces vigorous bubbling.
  • Enough heat is released for the sodium to become molten.

The colourless solution produced is strongly alkaline because it contains sodium hydroxide, with a pH of about 13–14.

waterNaH2

Oxidation state

Sodium changes from oxidation state 00 in Na\ce{Na} to +1+1 in NaOH\ce{NaOH}.

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