Enzymes

01Enzymes

Biological catalysts

This section covers enzymes as protein catalysts, active sites and formation of enzyme–substrate complexes.

Enzymes as catalysts

Enzymes are biological catalysts and are globular proteins. They increase the rate of chemical reactions in living systems without being consumed.

The folded globular structure contains a region called the active site, where a reacting molecule can bind. The molecule that binds is the substrate.

When the substrate is held at the active site, an enzyme–substrate complex is formed.

enzymesubstrateactive site

Binding and reaction

A substrate must collide with the active site in a suitable orientation for effective binding and reaction to occur.

  • The substrate approaches the active site.
  • Binding produces the enzyme–substrate complex.
  • The reaction occurs while the substrate is associated with the enzyme.
  • The enzyme remains available for further reactions rather than being consumed.

Exam Tip: When describing an enzyme, state that it is a protein that acts as a biological catalyst. If the substrate is shown bound to the enzyme, identify the combined species as the enzyme–substrate complex.

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